Development at the pioneering paintings in supramolecular chemistry from the final twenty years or so, this monograph addresses new and recent
methods to anion coordination chemistry. Synthesis of receptors, organic receptors and metallareceptors, the energetics of anion binding, molecular constructions of anion complexes, sensing units are provided and computational reviews addressed to assist with the knowledge of the various riding forces accountable for anion complexation. The reader is promised an exact photograph of the cutting-edge for this intriguing and always evolving box of supramolecular anion coordination chemistry. the subjects variety from ion channels to selective
sensors, making it appealing to all researchers and PhD scholars with an curiosity in supramolecular chemistry.Content:
Chapter 1 facets of Anion Coordination from old views (pages 1–73): Prof. Dr. Antonio Bianchi, Prof. Dr. Kristin Bowman?James and Prof. Dr. Enrique Garcia?Espana
Chapter 2 Thermodynamic elements of Anion Coordination (pages 75–140): Prof. Dr. Antonio Bianchi and Prof. Dr. Enrique Garcia?Espa?na
Chapter three Structural facets of Anion Coordination Chemistry (pages 141–225): Rowshan Ara Begum, Sung okay Kang, Victor W. Day and Prof. Dr. Kristin Bowman?James
Chapter four artificial innovations (pages 227–287): Andrea Bencini and Jose M. Llinares
Chapter five Template Synthesis (pages 289–320): Jack okay. Clegg and Leonard F. Lindoy
Chapter 6 Anion–? Interactions in Molecular popularity (pages 321–361): David Qui?nonero, Antonio Frontera and Pere M. Deya
Chapter 7 Receptors for Biologically appropriate Anions (pages 363–464): Stefan Kubik
Chapter eight artificial Amphiphilic Peptides that Self?Assemble to Membrane?Active Anion Transporters (pages 465–519): George W. Gokel and Megan M. Daschbach
Chapter nine Anion Sensing by way of Fluorescence Quenching or Revival (pages 521–552): Valeria Amendola, Luigi Fabbrizzi, Maurizio Licchelli and Angelo Taglietti
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Additional resources for Anion Coordination Chemistry
3 Oxoanions Oxoanions have triangular, tetrahedral, or more complex shapes resulting from the association of different triangles or tetrahedrons that can be also accompanied by organic residues as in mono- and polynucleotides. On the other hand, if anions are conjugated bases of protic acids, they will undergo protonation processes and their negative charge will depend on their basicity constants. 1 logarithmic units for its ﬁrst, second, and third protonation steps, respectively . Therefore, phosphate exists only as a trivalent anion in a very basic pH range, while at neutral pH it is present in aqueous solution as a mixture of the monovalent and divalent forms.
Addition of the macrocycles brings about anodic shifts, whose magnitude depends on the stoichiometries of the complexes formed and on their stabilities. The interaction of the series of large polyazacycloalkanes aneN7 , aneN8 , aneN9 , aneN10 , aneN11 , and aneN10 (67–72) and their open-chain counterparts (101–104) in their protonated forms with a series of H N N H H N N H n n = 1, Me2hexaen n = 2, Me2heptaen n = 3, Me2octaen n = 4, Me2nonaen H N N H NH 101 102 103 104 cyanometallates and other anionic metal complexes was an illustrative early example of this chemistry presented by the Supramolecular Chemistry groups of Florence and Valencia during the years 1985–1995 [189–196].
These anions offer simple ways of analyzing the inﬂuence on host–guest afﬁnity of negative charge increases while other factors such as shape and geometry are kept essentially constant. For instance, apart from solvation effects, the only noticeable change when moving from [Fe(CN)6 ]3− to [Fe(CN)6 ]4− is the different net charge of both anions. In the same way, exchanging [Fe(CN)6 ]3− by [Co(CN)6 ]3− should be nonsigniﬁcant from a recognition point of view; both anions are octahedral and have a very close size.