By H Suschitzky; O Meth-Cohn; Great Britain. The Royal Society of Chemistry
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Additional info for a review of the literature abstracted between July 1980 and June 1981
Ioffe, Zh. Org. Khim, 1981, 17,436 (Chem. , 1981, 94, '71 Yu. P. Artsybasheva, I. V. Suvorova, and B. V. Ioffe, Zh. Org. , 1981, 17,435 (Chem. , 1981,94,208 079). G . Kresze and M. Roessert, Liebigs Ann. , 1981,58. Meier and H. Kolshorn, 2. , Teil. 8, 1980,35,1040. 192 016). 32 Heterocyclic Chemistry Preparation of Aziridines by Cyclization. g. '~~ H OH Me0,C C0,Me MeozcwcozMe C0,Me (228) --* v C 0 , M e H (229) Two routes to 9,lO-iminophenanthrene (230) have been described. The l ~ ~ method involves the conversion of (231) into its a,a-dichloroalkyl phenyl ketimine (232) followed by its reduction by LiAlH4 in ether.
1979, 1431. N. Kanehisa, N. Yasuoka, N. Kasai, K. Isomura, and H. Taniguchi, J. Chem. ,Chem. Commun,, 1980, 98. I. R. Dunkin and P. C. P. Thornson, J. Chem. ,Chem. , 1980,499. E. Schaumann and H. Mrotzek, Tetrahedron, 1979,35, 1965. E. Schaumann, S. Grabley, M. Henriet, L. Ghosez, R. Touillaux, J. P. Declercq, G. Van Meerssche, J. Org. , 1980, 45, 2951. 38 Heterocyclic Chemistry \ FN /c=c=c \ Bu' NC But (274) CN A number of reactions of 2,2-dimethyl-3-phenylazirine(280) are shown in Scheme 17.
Ono, H. Tazawa, and S. , 1979,4661. -Predictions as to the reactivities and stabilities of oxirans continue to engage the interest of theoretical chemists. ]-derivatives, quantum and molecular mechanics have been used to show that cycloheptene oxide exists in a b ~ a t - c h a iand r ~ ~cyclohexene oxide in a half-chair'" conformation. lo2 Hydrogenbonding of this type facilitates opening of the oxiran ring at either carbon atom but particularly affects C-1. r. lo3 The coupling constant J(HA-HB) is at a maximum for (116) in Bu'OH, where intramolecular H-bonding predominates.